Since I love to play games in my PC, moving completely to GNU/Linux was tough for me. But with PlayStation emulators like PSX and ePSXe I can play hundreds of games with ease. Here is the way how I setup ePSXe
Extract it and click epsxe to run it. Choose File -> RUN ISO to play the game whose ISO image is with you. You need libgtk* libraries and gtk packages to run the emulator smoothly.
Another emulator that works fine with *.BIN images is the PSX emulator.
NOTE: You need to have a PlayStation bios file in the bios folder in order to play